Separate from companies and conspiracies. Dates are first clear documented appearance of the idea, not “the idea became true.”

WhenIdeaStatusWhere on this site
Late 18th c.Graphite is elemental carbon, not leadWell-supported consensuspre-chemistry
1859Graphite can be oxidized into a lamellar oxideWell-supportedbefore-1900
1947Single graphite layer as a calculable electron system; linear bands at zone cornersWell-supported theory1947
1960s–80sStrict 2D crystals vs Mermin–Wagner-type expectationsContext; often over-simplified in pop history1963-2003
1962 / 1986Monolayer carbon from oxide; name grapheneWell-supported1962
2004–2005Isolated monolayer on insulator + Dirac-fermion transportWell-supported experiment2004 · 2005-2009
2005+Graphene as a platform for other 2D crystals and heterostructuresWell-supported research program2010
2010s“Graphene replaces silicon” as an engineering idealMostly unmet; band-gap and contact limits2011-2012
2013+Flagship-scale coordinated application pushWell-supported as a program2013
2015Holey graphene as a molecular stencil / weed barrier on goldWell-supported methodholey-graphene-molecular-stencil

Add a row when a new picture appears (new Hamiltonian, new process ideal, new “what graphene is for”), not when a company repeats a slide.